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Measuring salt content of the seawater by a snap shot
 

Seawater and beaches are the wonders of nature. Populations from all parts of the world flock to the beaches for bathing, etc., and enjoy with this mighty nature. After bathing, however, one feels like having a freshwater shower to remove the sticky feeling that is due to formation of a thin layer of salt over the body. While one wishes to remove it from the body, the salt is an important constituent in our food that originates from the seawater. How much is the salt in seawater? Will this resource also be scarce like other natural resources? Forget it! There is so much of salt in the water that it is impossible to really become 'scarce'. It is said, "if the oceans around continents get dried up completely, enough salt would be left behind to build a 180-mile-tall, one- mile-thick wall around the equator!" So no worry at all. This is because the seawater consists on an average 3.5% of the salt. Chemically speaking, 90% of this salt is Sodium Chloride - the ordinary table salt.

Although, the salt concentration in seawater (or salinity in scientific terminology) is 3.5% as indicated, it varies slightly from place to place and season to season. This variation in a given oceanic region is mainly due to the net effect of evaporation, precipitation, river runoff and melting of ice. While evaporation of water increases the salt content, the precipitation (ie. rainfall over the water body), river runoff into the sea and melting of sea ice dilute the saltwater and lowers the salinity. In the earliest years, salinity was measured using chemical titration of the water sample with silver nitrate. The best measurements of salinity from titration give salinity with an accuracy of ± 0.02 psu (practical salinity units - in which salt concentration is measured). In this unit, ocean water has an average salinity of 35 psu.

The advancement in the technology helped developing an instrument that replaced the titration method of measuring salinity of seawater. This instrument is called 'CTD profiler'. Each of the alphabets in the 'CTD' stands for measuring the properties of seawater Conductivity (C) and Temperature (T) with Depth (D) in the sea. This instrument is lowered from ships in the seawater to a desired depth to get profiles of temperature and salinity. Interestingly, this instrument does not measure salinity directly, but by measuring conductivity (how easily electric current passes through the seawater), scientists can get a measurement of that water sample's salinity because electric current passes much more easily through water with a higher salt content. So, if we know the conductivity of the water, we can calculate how much salt is there in the water.

Having confirmed that there is enough salt available for us for future consumption why do we worry of measuring salt content of seawater at different places? Yes, the difference in the salinity in the seawater, and its understanding is very important to all of us. Because, the circulation of seawater from one place to other place, formation of watermasses in specific oceanic regions, the occurrence of EI Nino's in Pacific, even the monsoon rainfall over India - all that have an important bearing on the salinity - especially sea surface salinity (SSS) - of the water at a particular place in the oceans. In order to know / predict the likely changes in salinity and particularly the SSS, scientists build models and simulate the conditions in the sea as salinity is an important variable along with temperature and pressure. Though it was possible since long to measure sea surface temperature (SST) from satellite remote sensing techniques, the data on salinity poses a problem always and block in the development of prediction models at micro-level. In development of models for circulation, etc., the salinity was chosen from the climatological atlases. It is no doubt that the World Ocean Atlas does provide some data on salinity collected in a place by ships for years. But it is also very scanty. If we check how much observations existed for 1 x1 grid over global oceans, one ends up in knowing that only 70% of them (grids) have some data and some have not been observed more than once for reconfirmation!

Salinity is especially an important variable for simulating the tropical sea dynamics. It is no doubt that the American and European satellite missions that are planned for the year 2008 would then start providing salinity data. But this does not prevent enthusiastic scientists to stop thinking on other alternatives.

The scientists at NIO, along with their colleagues in other research laboratories, had a breakthrough in estimating the sea surface salinity using the existing satellite images data. The new technique uses a set of algorithms (based on statistical relationships) relating the atmospheric convection parameter, the Outgoing Longwave Radiation (OLR), the geopotential thickness of the oceanic near surface stratified layer (also called effective oceanic layer - the EOL), freshwater flux (precipitation minus evaporation), and the climatological sea surface salinity. They developed algorithms for four sub-regions in the tropical Indian Ocean. Using all the available data at hand, they have been able to estimate salinity at 2.5 x 2.5 grid in the tropical Indian Ocean.

Figure 1 Comparison of the observed (WOCE), climatological (WOA98), estimated sea surface
salinity, and estimated sea surface salinity with 1-month lag (a, b) along WOCE I1 section (~8°N in the AS (left) and ~10°N in the BOB (right)) during 13 September to 14 October 1995, (c) along WOCE I2 section (~8°S) during 5 December 1995 to 20 January 1996, and (d) along WOCEI3 section (~20°S) during 27 April to 5 June 1996. The data points represent the center of the 2.5° x 2.5° grids along the sections
.

The sea surface salinity was estimated for the period 1995-2000 using the OLR data for 22 years (1979-2000). This was then compared with the simultaneously available salinity data (Figure 1), collected during World Ocean Circulation Experiment (WOCE), during Bay of Bengal Monsoon Experiment (BOMMEX), etc. On the basis of the results, the seasonal and interannual variability of the estimated sea surface salinity was also arrived at.

The technique was found to be of great value in estimating sea surface salinity in future in the tropical oceans. The monthly maps of estimated sea surface salinity were found to be accurate than available model simulations or maps made from conventional methods. In long run, this method would be useful to the researchers and modelers ultimately to understanding the circulation of oceanic waters on different time scales.

     

To consult original article, refer :
Murty, V.S.N.; Subrahmanyam, B.; Tilvi, V.; O'Brien, J.J. A new technique for the estimation of sea surface salinity in the tropical Indian Ocean from OLR . J. Geophys. Res. (C: Oceans): 109; 2004; 26 pp.